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Temperature dependence of vibration—vibration energy exchange probabilities among highly excited levels: CO(υ-1) + CO(1) → CO(υ) + CO(0)

✍ Scribed by H.K. Shin

Publisher: Elsevier Science
Year: 1979
Tongue: English
Weight: 465 KB
Volume: 64
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(79)87267-x

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✦ Synopsis

The temperature dependence of onequantum V -V mcr~) exchange probxbdiries imohing highly excited CO molrcules m CO(u-1) I CO(l) -CO(u) f CO(O) has been investigated. I'or u = 8, the probabdity increases by an order of magnitude orer the temper&ture r.mse 100-3000 I;; for a = 15, the increase is nearly tno crders of mzgnitude. The dependence of energy ewh.mge probabilities on u is not stron,. 0 The contribution of moleculx attraction dominates that of repulsion in the process particularly at Ioxxer temperatures.

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