Temperature dependence of the structure of the l-alanine radical: ESR study
β Scribed by Koichi Itoh; Ichiro Miyagawa
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- English
- Weight
- 370 KB
- Volume
- 190
- Category
- Article
- ISSN
- 0022-2860
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π SIMILAR VOLUMES
The ESR spectrum of the tricyclohexylmethyl radical was obtained from tricyclohexylmethyl chloride and was studied in solution in the range 275-455 K. It has a half-life of about 30 min at room temperature. The complex hyperfioe structure of the radical was analysed with the help of MNDOWHF calculat
The ESR lineshape of spin-correlated radical pairs (RP) diffusing in a small volume is calculated within the sudden perturbation approach for space dimensionalities D = 1, 2, 3. It is shown that in 2D and 3D models the RP spin dynamics are described by a Bioch-type equation quite accurately. A simpl