Temperature Dependence of The Solubility and Complex Formation of Silver Chloride in Dimethyl Sulfoxide

✍ Scribed by N. A. Rumbaut; H. L. Peeters

• Publisher: Wiley (John Wiley & Sons)
• Year: 2010
• Weight: 358 KB
• Volume: 79
• Category: Article
• ISSN: 0037-9646
• DOI: 10.1002/bscb.19700790106

✦ Synopsis

The temperature dependence of the solubility product of AgCl in pure dimethyl sulfoxide in the range 25 to 70 "C has been investigated. Thermodynamic values at zero ionic strength are estimated. Formation constants for the AgCI2-complex, existing in excess chloride are also tabulated as a function of temperature. The entropy and enthalpy data thus obtained are discussed in terms of ionic solvation. 1NTRODUCTlON