The Arrhenius parameters of the bimolecular rate constants for the decay of several phenoxyl radicals in aqueous solution were measured. The p-halophenoxyl radicals (F, C1, and Br) decay in a diffusion controlled reaction as the activation energies are the same as that of diffusion of water (16 ? 1.
Temperature dependence of the relative rate constants of the reactions of alkanes with oh radicals in aqueous solution
β Scribed by V. L. Lobachev; Ya. V. Matvienko; E. S. Rudakov
- Publisher
- Springer
- Year
- 2009
- Tongue
- English
- Weight
- 323 KB
- Volume
- 45
- Category
- Article
- ISSN
- 0040-5760
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