𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Temperature dependence of the relative rate constants of the reactions of alkanes with oh radicals in aqueous solution

✍ Scribed by V. L. Lobachev; Ya. V. Matvienko; E. S. Rudakov


Publisher
Springer
Year
2009
Tongue
English
Weight
323 KB
Volume
45
Category
Article
ISSN
0040-5760

No coin nor oath required. For personal study only.


πŸ“œ SIMILAR VOLUMES


Temperature dependence of the self-decay
✍ Z. B. Alfassi; L. C. T. Shoute πŸ“‚ Article πŸ“… 1993 πŸ› John Wiley and Sons 🌐 English βš– 728 KB

The Arrhenius parameters of the bimolecular rate constants for the decay of several phenoxyl radicals in aqueous solution were measured. The p-halophenoxyl radicals (F, C1, and Br) decay in a diffusion controlled reaction as the activation energies are the same as that of diffusion of water (16 ? 1.

Rate constants for the OH reactions with
✍ S. Gligorovski; D. Rousse; C. H. George; H. Herrmann πŸ“‚ Article πŸ“… 2009 πŸ› John Wiley and Sons 🌐 English βš– 344 KB πŸ‘ 1 views

## Abstract The kinetics of the oxidation of functionalized organic compounds of atmospheric relevance by the hydroxyl radical (OH) was measured in the aqueous phase. Competition kinetics, using the thiocyanate anion (SCN^βˆ’^) as competitor, was applied using both a laser flash photolysis long path

Rate constants for some reactions of fre
✍ Pichai Maruthamuthu; S. Padmaja; Robert E. Huie πŸ“‚ Article πŸ“… 1995 πŸ› John Wiley and Sons 🌐 English βš– 443 KB πŸ‘ 1 views

The kinetics of the acqueous-phase reactions of the free radicals .OH, .Cl,, and SO; . with the halogenated acetates, CHzFCOO-, CHF2COO-, CF3COO-, and with CHzClC00-, CHClzC00-, CC13COOwere investigated. Generally, the reactivity decreases with increasing halogen substitution and is in the order k(.

Rate constants of the reactions of OH ra
✍ S. DΓ³BΓ©; T. TurΓ‘nyi; A. A. Iogansen; T. BΓ©rces πŸ“‚ Article πŸ“… 1992 πŸ› John Wiley and Sons 🌐 English βš– 372 KB πŸ‘ 1 views

The kinetics of the reactions of hydroxy radicals with cyclopropane and cyclobutane has been investigated in the temperature range of 298-492 K with laser flash photolysidresonance fluorescence technique. The temperature dependence of the rate constants is given by k l = (1.17 ? 0.15) x T3'' exp[-(1

Rate constants for the reactions of OH r
✍ Tomohiro Ohta πŸ“‚ Article πŸ“… 1984 πŸ› John Wiley and Sons 🌐 English βš– 417 KB πŸ‘ 2 views

Relative rate constants for the reactions of hydroxyl radicals with a series of alkyl substituted olefins were measured by competitive reactions between pairs of olefins a t 298 r 2 K and 1 atmospheric pressure. Hydroxyl radicals were produced by the photolysis of H,O, with 254-nm irradiation. The o