Relative rate coefficient data have been obtained for the reactions Br Ο© RCHO : RCO Ο© HBr for a series of aldehydes: HCHO, reaction (1); CH 3 CHO, reaction (2); CH 3 CH 2 CHO, reaction (3); CH 3 CH 2 CH 2 CHO, reaction (4). Measurements were made over the temperature range 240-300 K in an environmen
Temperature Dependence of the Rate Coefficients for the Reactions of Atomic Bromine with Toluene, Tetrahydrofuran, and Tetrahydropyran
β Scribed by Giri, Binod Raj; Roscoe, John M.
- Book ID
- 127370060
- Publisher
- American Chemical Society
- Year
- 2009
- Tongue
- English
- Weight
- 247 KB
- Volume
- 113
- Category
- Article
- ISSN
- 1089-5639
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Rate coefficients for the reaction of Cl atoms with CH 3 Cl (k 1 ), CH 2 Cl 2 (k 2 ), and CHCl 3 (k 3 ) have been determined over the temperature range 222-298 K using standard relative rate techniques. These data, when combined with evaluated data from previous studies, lead to the following Arrhen
## Abstract The rate coefficient for the gasβphase reaction of chlorine atoms with acetone was determined as a function of temperature (273β363 K) and pressure (0.002β700 Torr) using complementary absolute and relative rate methods. Absolute rate measurements were performed at the lowβpressure regi
Kcccivcd 7 hlarch 1977 The rate constant Ior the rrnction Br + 0~ -BrO + 02 has been mcawrcd over the tempcraturc rdrye 224 to 522 EC in a dxhargc llow systcni ucmk a IKISF spcctrornctcr a~ B detector. Rcsultg, c\pre%scd in the form kr = (3.34 c O-40) X IO-\*' X cxp[ -(978 1. 36)/T] cn13 s-' , arc c
A laser-flash photolysis/UV absorption technique has been used to study the temperature dependence (from T Ο 300 -470 K) of the self-reaction kinetics of representative primary, secondary, and tertiary β€-hydroxyperoxy radicals: The following Arrhenius expressions were derived for the rate coefficie