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Temperature dependence of the phosphorus-31 chemical shifts of nucleic acids. A probe of phosphate ester torsional conformations

✍ Scribed by Gorenstein, David G.; Findlay, John B.; Momii, Robert K.; Luxon, Bruce A.; Kar, Debojyoti


Book ID
127310649
Publisher
American Chemical Society
Year
1976
Tongue
English
Weight
891 KB
Volume
15
Category
Article
ISSN
0006-2960

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The temperature dependence of the 13 C chemical shifts in tristearin and methyl stearate has been investigated in both the melt and solution phases. Intramolecular conformational changes dominate the observed behaviour and there is little evidence for intermolecular interactions even in the melt pha