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Temperature dependence of the lifetimes of the ligand-field states of tris(1,10-phenanthroline)iron(II)

✍ Scribed by M.A. Bergkamp; B.S. Brunschwig; P. Gütlich; T.L. Netzel; N. Sutin

Publisher: Elsevier Science
Year: 1981
Tongue: English
Weight: 387 KB
Volume: 81
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(81)85346-8

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✦ Synopsis

The lifetimes of the excited states produced by 527 mn excitation of tris(l,lOphenanthroLine)iron(II) have been measured in a 4 : 1 (v/v) ethanol/methanol mixture in the 14-295 K temperature range. The results are analyzed in terms of the < 10 ps population of l&and-field (LF) states from the initially generated metal-to-&and charge-transfer (MLCT) sta:es.

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