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Temperature dependence of the lattice dynamics of Rb3C60

✍ Scribed by J.W. White; G. Lindsell; L. Pang; A. Palmisano; D.S. Sivia; J. Tomkinson

Publisher: Elsevier Science
Year: 1992
Tongue: English
Weight: 418 KB
Volume: 191
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(92)85374-j

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✦ Synopsis

The phonon density of states of Rb,& has been measured above and below the superconducting phase transition temperature of 29 K and in the energy transfer range 1 < AE< 300 meV at an energy resolution AE/E= 2%. Marked changes in the molecular vibrational spectrum of C6,, are observed upon intercalation with rubidium. In particular the H, modes at 54 meV and the T,, mode at 66 meV are strongly quenched and other modes are broadened and shifted. Distinct changes in the H,, T,, modes near 180 meV and the H, modes near I35 meV are observed on passing through the superconducting transition temperature region. These changes strongly suggest the involvement of molecular motions in the superconductivity of these materials.

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