Temperature dependence of the IR driven cis-trans isomerization of nitrous acid (HONO)
โ Scribed by Botan, Virgiliu; Hamm, Peter
- Book ID
- 118020848
- Publisher
- American Institute of Physics
- Year
- 2008
- Tongue
- English
- Weight
- 371 KB
- Volume
- 129
- Category
- Article
- ISSN
- 0021-9606
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๐ SIMILAR VOLUMES
The rate of y-ray-induced trans -cis isomerization of stilbene in dilute toluene solutions from -95o to A1OOo shows a maximum at about -25O. The results are interpreted in terms of interplay of opposing reactions. and of the role of triplet toluene.
The variations of the geometrical (bond lengths and angles), electronic (dipole moment magnitude and orientation) and chemical (acidity) data whi-h are experimentally observed when going from the cis to the frets isomer of nitrous acid are fully reproduced within the fmmework of semi-empiricnl CNDO/