Temperature Dependence of the Deuterium Quadrupole Coupling Constants and the Correlation Times for Neat Formamide
β Scribed by Hansen, Mary J.; Wendt, Mark A.; Farrar, Thomas C.
- Book ID
- 126928618
- Publisher
- American Chemical Society
- Year
- 2000
- Tongue
- English
- Weight
- 89 KB
- Volume
- 104
- Category
- Article
- ISSN
- 1089-5639
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π SIMILAR VOLUMES
Using a self-consistent NMR method, it is now possible to determine both the deuterium quadrupole coupling constant as well as the rotational dynamic isotope effect in liquids. We successfully tested the method on benzene for temperatures between 280 K and 293 K. The average value of 185(3) kHz for
The tempcrdture dcpendcnce of deutermm nuclear relaxation times in select!vcly dcutcratcd toluenc and chlorobcnzene IS studied. It is shown that the temperature behdviour of molecular reorientation times can be described by the method of