✦ LIBER ✦

Temperature dependence of the 5T2 - 1A1 energy separation at the ground-state crossover in [FeIIN6] complexes

✍ Scribed by E. König; S. Kremer

Publisher: Elsevier Science
Year: 1971
Tongue: English
Weight: 250 KB
Volume: 8
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(71)85022-4

No coin nor oath required. For personal study only.

✦ Synopsis

The energy separation E between the terms sr2 and IAl at the ground-state crossover in Fen-N61 complexes is shown to be strongly temperature dependent.. This is consistent with a simultaneously occurring change of the Fe-N bond distance which was demonstrated. in one case. bv X-ra structure methods. It is proposed that similar results should be expeckd at the crossover ti d 4 dg, d6 and d7 , configurations.

📜 SIMILAR VOLUMES

Synthesis, Structure and Characterizatio

Synthesis, Structure and Characterizations in Solid State and Solution of Dinuclear Pentacoordinated FeII and MnII Complexes and of a Linear Tetranuclear FeIII Complex Obtained with the Ligand N,N,N′,N′-Tetrakis[(6-methyl-2-pyridyl)methyl]propane-1,3-diamine

✍ Véronique Balland; Elodie Anxolabéhère-Mallart; Frédéric Banse; Eric Rivière; So 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 196 KB 👁 2 views

## Abstract Two neutral complexes [(L~6~^3^4M)Fe~2~Cl~4~]·2H~2~O·2CHCl~3~ (1) and [(L~6~^3^4M)Mn~2~Cl~4~]·CH~3~CN (2) have been synthesized {L~6~^3^4M = __N__,__N__,__N′__,__N′__‐tetrakis[(6‐methyl‐2‐pyridyl)methyl]propane‐1,3‐diamine} and their molecular structures established by X‐ray crystallogr