β Scribed by D.C. Clary; D. Smith; N.G. Adams
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Rate coefficients for the reaction of Cl atoms with CH 3 Cl (k 1 ), CH 2 Cl 2 (k 2 ), and CHCl 3 (k 3 ) have been determined over the temperature range 222-298 K using standard relative rate techniques. These data, when combined with evaluated data from previous studies, lead to the following Arrhen
A laser-flash photolysis/UV absorption technique has been used to study the temperature dependence (from T Ο 300 -470 K) of the self-reaction kinetics of representative primary, secondary, and tertiary β€-hydroxyperoxy radicals: The following Arrhenius expressions were derived for the rate coefficie
Rate constants for several reactions of inorganic radicals with inorganic anions in aqueous and aqueousiacetonitrile solutions have been measured as a function of temperature by laser flash photolysis. The reactions studied were (1) C12'-+ N3-, (2) Br2'-+ N3-, (3) C12'-+ SCN-, (4) Br2'-+ SCN-, (5) S
Relative rate coefficient data have been obtained for the reactions Br Ο© RCHO : RCO Ο© HBr for a series of aldehydes: HCHO, reaction (1); CH 3 CHO, reaction (2); CH 3 CH 2 CHO, reaction (3); CH 3 CH 2 CH 2 CHO, reaction (4). Measurements were made over the temperature range 240-300 K in an environmen