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Temperature Dependence of Proton NMR Chemical Shift As a Criterion To Identify Low-Barrier Hydrogen Bonds

✍ Scribed by Garcia-Viloca, Mireia; Gelabert, Ricard; González-Lafont, Àngels; Moreno, Miquel; Lluch, José M.


Book ID
127123627
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
100 KB
Volume
120
Category
Article
ISSN
0002-7863

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Using low-temperature UV, 1 H and 15 N NMR spectroscopy, we studied the easily polarizable bond of the labeled Mannich base[ 15 N] 2-(N,Ndiethylaminomethyl)-3,4,6-trichlorophenol (Cl 3 MB) dissolved in dichloromethane and in a 2 : 1 mixture of CDF 3 and CDClF 2 . Whereas at high temperature the mol