The intermolecular potential derived by Leavitt from irreducible tensor methods is used in a semiclassical impact theory to calculate the \(\mathrm{O}_{2^{-}}\)and \(\mathrm{N}_{2}\)-broadening coefficients of the \({ }^{q} P(J, K)\) and \({ }^{9} R(J, K)\) lines belonging to a parallel band of \(\m
Temperature Dependence of N2and O2Broadening Coefficients of Ozone
β Scribed by A. Barbe; L. Regalia; J.J. Plateaux; P.Von Der Heyden; X. Thomas
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 210 KB
- Volume
- 180
- Category
- Article
- ISSN
- 0022-2852
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β¦ Synopsis
The nitrogen and oxygen broadening coefficients of ozone have been experimentally obtained at two low temperatures (227 and 186 K) in the n 1 / n 3 band, located at 2110 cm 01 . Thirty-five transitions have been chosen to derive the n coefficient defined by a(T ) Γ a(T o )r(T o /T ) n . This is found, for both N 2 and O 2 , to be n Γ 0.72 { 0.08, where 0.08 is two standard deviations. This value is accurate enough for atmospheric applications.
π SIMILAR VOLUMES
Room temperature measurements of self-, air-, and oxygen-broadening coefficients are reported for 101 pure rotational absorption lines for 16 O 3 covering a range of 7 β€ J β€ 34 and 3 β€ K -1 β€ 11 in the spectral region 50 to 90 cm -1 . In addition, the temperature dependence of the coefficients has b
Absorption linewidths associated with microwave transitions across -doublets and pure rotational transitions of the free hydroxyl radical OH perturbed by N 2 , O 2 , and Ar are computed for temperatures ranging from 194 to 300 K within the framework of the Robert-Bonamy semiclassical formalism using
\(\mathrm{N}_{2}\)-broadening coefficients have been measured for 28 lines of \(\mathrm{HCN}\) at \(203 \mathrm{~K}\) in the \(P, Q\). and \(R\) branches of the \(\nu_{2}\) band, using a tunable diode-laser spectrometer. Semiclassical calculations of these collisional broadenings have been performed