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Temperature dependence of intersystem crossing of pyrene

โœ Scribed by Hiroshi Hirano; Tohru Azumi

Publisher
Elsevier Science
Year
1982
Tongue
English
Weight
68 KB
Volume
90
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

The temperature dependence of the rate constant for intersystem crossmg from St of pyrene w;ts dctcmuncd by mans of a method proposed prcnously. In contrast to the conclusions of Stevens, Thomaz and Jones, and of Kropp, Dawson snd Wmdsor, we conclude that both temperature-mdependenr and trmpcr~turedcpcndenr incersysrcm crossmg processes exist. These two processes contnbute equally nt -150 L

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On the role of low-frequency modes in th
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โœ H. Kono; S.H. Lin; E.W. Schlag ๐Ÿ“‚ Article ๐Ÿ“… 1988 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 529 KB

The strong temperature dependence of T, -63, intersystem crossing (ISC) and the energy dependence of T, +S, under collisionfree conditions is semiquantitatively discussed on the basis of a model in which consideration is given to low frequency modes that undergo a large increase in frequency in goin