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Temperature dependence of hydrogen evolution reaction on nickel oxide electrode in sealed nickel/cadmium cells

✍ Scribed by M.S. Suresh; S. Sathyanarayana


Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
208 KB
Volume
45
Category
Article
ISSN
0378-7753

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✦ Synopsis


~stract

The impedance of sealed nickel/cadmium cells around a cell e.m.f, of 0.0 V was measured at five different temperatures between -10 and +30 °C. The results show that the behaviour is similar at all temperatures. Based on the experimental results, the relation between charge-transfer resistance (R~) and temperature (T) has been established for the Volmer reaction. Further, the value of cathodic transfer coefficient (a) has been estimated.