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Temperature dependence of cyanogen radical reactions with selected alkanes: CN reactivities towards primary, secondary and tertiary CH bonds

✍ Scribed by David L. Yang; Tao Yu; Niann S. Wang; M.C. Lin

Publisher: Elsevier Science
Year: 1992
Tongue: English
Weight: 711 KB
Volume: 160
Category: Article
ISSN: 0301-0104
DOI: 10.1016/0301-0104(92)80131-e

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## Abstract The kinetics of C~6~H~5~ reactions with __n__‐C~__n__~H~2__n__+2~ (__n__ = 3, 4, 6, 8) have been studied by the pulsed laser photolysis/mass spectrometric method using C~6~H~5~COCH~3~ as the phenyl precursor at temperatures between 494 and 1051 K. The rate constants were determined by k