Temperature Dependence of Collision-Broadened Lines of Phosphine
β Scribed by A. Levy; N. Lacome; G. Tarrago
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- English
- Weight
- 509 KB
- Volume
- 166
- Category
- Article
- ISSN
- 0022-2852
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β¦ Synopsis
As an exwnsion of a previous study at room temperature, high-resolution FT spectra of phosphine have been obtained under lower temperature conditions, namely near 235 and (175 \mathrm{~K}). The spectral range investigated, (1950-2150 \mathrm{~cm}^{-1}), covers mainly the three weak transitions (2 \nu_{2}, \nu_{2}+\nu_{4}), and (2 v_{4}) which contribute, along with the strong bands (\nu_{1}) and (\nu_{3}), to the absorption in the observational window of Jupiter near (4-5 \mu \mathrm{m}). About 800 lines were analyzed by means of a nonlinear leastsquares fit procedure in order to extract their individual spectral parameters. The retrieved values of the linewidths, along with those previously determined from the spectra at room temperature. were used to derive the temperature dependence of both (\mathrm{H}{2}) and (\mathrm{He}) broadening of (\mathrm{PH}{3}) lines. The broadening coefficients were shown to fit closely the usual "exponential" relation (\gamma(T)=) (\gamma_{0}\left(T_{0}\right) \cdot\left(T_{0} / T\right)^{n}). Careful inspection of the values obtained for the (n) exponent shows that, for a single value of (J, n) is nearly (K) independent within the series of lines of a given rotational type. Also, for a given (J) it does not seem to exhibit any noticeable variation with the type of rotational transitions under study. Only when considering the dependence of the (K)-averaged values of (n) as a function of (J) is a slight variation observed, with a clear trend of (n) to decrease as (J) values increase. However, in the range of (J) values investigated here ((J \leqslant 13)), the magnitude of variation of (n) remains small. Accordingly, for the purpose of planetary spectra modeling, it seems quite reasonable to adopt a mean value of the (n) exponent for any (J) and (K). From the present measurements, we propose the values (n=0.73) and (n=0.30) for (\mathbf{H}_{2}) broadening and He broadening. respectively. (c) 1994 Academic Press. Inc.
π SIMILAR VOLUMES
The temperature dependence of lineshift and broadening of the rovibrational transitions R( ) and R(20) of the CO fundamental band, perturbed by Ar, N 2 , O 2 , and H 2 , have been measured with high frequency accuracy and at temperatures between 160 and 270 K in steps of 20 K. A wavelength stabilize