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Temperature-Controlled Selective Reduction of Arenesulfonyl Chlorides Promoted by Samarium Metal in DMF.

โœ Scribed by Yongjun Liu; Yongmin Zhang


Book ID
101942806
Publisher
John Wiley and Sons
Year
2003
Weight
112 KB
Volume
34
Category
Article
ISSN
0931-7597

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โœฆ Synopsis


Abstract

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๐Ÿ“œ SIMILAR VOLUMES


Temperature-controlled selective reducti
โœ Yongjun Liu; Yongmin Zhang ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 135 KB

Promoted by samarium in DMF, arenesulfonyl chlorides can be selectively reduced to diaryldisulfones, diarylthiosulfonates and diaryldisulfides in good to excellent yields by reaction temperature control without the need to pretreat or activate the metallic samarium.