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Temperature broadening of a photochemical hole in the spectrum of H2-octaethylporphin in polystyrene between 0.05 and 1.5 k

✍ Scribed by A. Gorokhovskii; V. Korrovits; V. Palm; M. Trummal

Publisher: Elsevier Science
Year: 1986
Tongue: English
Weight: 467 KB
Volume: 125
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(86)85171-5

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✦ Synopsis

The temperature dependence between 0.05 and 1.5 K of the width of a photochemical hole has been studied in the spectrum of H,-octaethylporphin impurity in an amorphous polystyrene matrix. At T= 0.5 K. the holewidths were 26 MHz for X, = 620.1 nm and 34 MHz for X, = 621.8 nm, exceeding the lifetime-limited value of 10.6 MHz. The temperature dependence has two crossovers in the range 0.09 to 0.36 K.

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