Temperature and field dependent 1H-NMR relaxation data as probes of prostaglandin motional parameters in aqueous media

Orientations of the principal components

Orientations of the principal components of electric field gradients and internal motions in dihydrogen ligands from the 2H T1 NMR relaxation data in solution

✍ Vladimir I. Bakhmutov 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 123 KB

## Abstract The deuterium spin–lattice relaxation times in (D~2~) ligands of W, Ru and Os complexes are reviewed and analyzed in terms of the fast internal (D~2~) motions: free rotation, librations and 180° jumps. The analysis was performed using quadrupolar coupling constant (__DQCC__) parameters