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TDA-1 catalysis in Smiles rearrangement of N-arylphenoxyamides. Accelerating effect of the 2,4,6-trichloro substitution

✍ Scribed by A Greiner

Publisher: Elsevier Science
Year: 1989
Tongue: French
Weight: 244 KB
Volume: 30
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)95282-1

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✦ Synopsis

Attempted N-alkylation of 3-(2,4,6-trichlorophenoxyacetamido) pyridine, with TDA-1 catalysis, yielded surprisingly N-alkylated 3-(2,4,6-trichLorophenyLamino)pyridines through a Smiles rearrangement.

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