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Tb3O2Cl[SeO3]2 and Tb5O4Cl3[SeO3]2: Oxide Chloride Oxoselenates(IV) of Trivalent Terbium with “Lone-Pair” Channel or Layer Structures.

✍ Scribed by Joseph Wontcheu; Thomas Schleid


Publisher
John Wiley and Sons
Year
2005
Weight
10 KB
Volume
36
Category
Article
ISSN
0931-7597

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Tb2Se2O7: Terbium(III) Oxide Oxoselenate
✍ Joseph Wontcheu; Thomas Schleid 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 German ⚖ 168 KB

The colourless title compound Tb 2 Se 2 O 7 (ϵ Tb 2 O-[SeO 3 ] 2 , terbium(III) oxide oxoselenate(IV)) was obtained by reacting a mixture of Tb 4 O 7 , Tb and SeO 2 in a 3:2:14-molar ratio at 850 °C for seven days in an evacuated silica vessel as needle-shaped single crystals. It crystallizes tetrag