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Tautomerism, structure in solution and in the solid state of 1:9,5:10-anthradipyrazole

✍ Scribed by Alkorta, Ibon; Elguero, José

Book ID
121569910
Publisher
Springer
Year
2014
Tongue
English
Weight
641 KB
Volume
25
Category
Article
ISSN
1040-0400

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The tautomerism of 1H-pyrazole-3(5)-(N-t
The tautomerism of 1H-pyrazole-3(5)-(N-tert-butyl)carboxamide in the solid state and in solution
✍ Rosa M. Claramunt; M. Ángeles García; Concepción López; Swiatoslaw Trofimenko; G 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 130 KB

## Abstract The X‐ray crystal structure of 1__H__‐pyrazole‐3‐(__N‐tert__‐butyl)‐carboxamide was determined. In the solid state, the ^13^C and ^15^N CP/MAS NMR spectra correspond to this tautomer. In solution, both tautomers are present in a ratio that depends on the temperature (at 293 K, 90% 3‐sub