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Tautomerism of β-dicarbonyl and β,β’-tricarbonyl compounds in protogenic media: The prototropy of hydroxonium derivatives of keto-enols

✍ Scribed by Gulyakevich, O. V.; Mikhal’chuk, A. L.


Book ID
110160006
Publisher
Springer
Year
2007
Tongue
English
Weight
207 KB
Volume
415
Category
Article
ISSN
0012-5008

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Substituent effects in keto-enol tautome
✍ M. Bassetti; G. Cerichelli; B. Floris 📂 Article 📅 1988 🏛 Elsevier Science 🌐 French ⚖ 437 KB

The enol content and equilibrium free energies for the keto-enol tautomerism have been determined for a series of 1,3-diketones, at 40 OC, in deuterochloroform and dimethylsulfoxide-d (DMSO), by lH n.m.r.. Compounds containing methyl, phenyl, t-butyl, E-thienyl, trifluorome t hyl and ethoxy groups h