The tautomerism of the synthesized 3-arylpyrimido[4,5-c]pyridazine-5,7(6H,8H)-diones (1a-d) and 3-aryl-7-thioxo-7,8-dihydro-6H-pyrimido[4,5-c]pyridazine-5-ones (2a-d) was studied in dimethyl sulfoxide (DMSO)-d(6). (1)H NMR spectra of 1a-d showed a clustered water molecule in the structure backbone t
Tautomerism in tetramic acids: 13C nmr determination of the structures and ratios of the tautomers in 3-acetyl-5-isopropylpyrrolidine-2,4-dione
✍ Scribed by Pieter S. Steyn; Philippus L. Wessels
- Publisher
- Elsevier Science
- Year
- 1978
- Tongue
- French
- Weight
- 215 KB
- Volume
- 19
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
Unsymmetrical cyclic s,B'-triketones (l_) can exist in solution as four different enolic forms, tiz. the external (a,b + c,d) and the internal (a + b; c # d) tautomers.'
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