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Tautomeric reaction equilibrium of ethyl acetoacetate in CO2–n-pentane and CO2–ethanol mixed solvents in the critical region

✍ Scribed by Hongping Li; Jun Liu; Xiaogang Zhang; Buxing Han; Zhimin Liu; Jun He; Liang Gao


Book ID
108445669
Publisher
Elsevier Science
Year
2002
Tongue
English
Weight
178 KB
Volume
200
Category
Article
ISSN
0378-3812

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✍ Hongping Li; Buxing Han; Jun Liu; Liang Gao; Zhenshan Hou; Tao Jiang; Zhimin Liu 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 198 KB 👁 2 views

The effects of pressure and of the composition of the CO2/ethanol mixed solvent in the critical region on the kinetics of the decomposition of 2,2'-azobis(isobutyronitrile) (AIBN) were studied at 333.15 K. The rate constants (kd) in the mixed solvent far from the critical point and in liquid n-hexan