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Tautomeric properties, conformations and structure of 2-hydroxyacetophenone methanesulfonylhydrazone

✍ Scribed by S. Alyar; Ü. Özdemir Özmen; N. Karacan; O.Ş. Şentürk; K.A. Udachin

Publisher
Elsevier Science
Year
2008
Tongue
English
Weight
368 KB
Volume
889
Category
Article
ISSN
0022-2860

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Tautomeric and conformational properties
Tautomeric and conformational properties of β-diketones
✍ Natalya V. Belova; Valeriy V. Sliznev; Heinz Oberhammer; Georgiy V. Girichev 📂 Article 📅 2010 🏛 Elsevier Science 🌐 English ⚖ 582 KB

Available literature data about keto-enol equilibrium in b-diketones with different substituents in b-positions (R1C(O)-CH 2 -C(O)R2) has been analyzed. It was concluded that substituents from group I (R = H, CH 3 , CF 3 , C(CH3) 3 ) strongly favour the enol tautomer, whereas substituents from group