Tautomeric and conformational equilibria in dinitrosomethane
โ Scribed by A.C. Fantoni; Walther Caminati
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 342 KB
- Volume
- 376
- Category
- Article
- ISSN
- 0022-2860
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In a recent note, Huisgen and coworkers have summarized the existing data concerning the equilibrium position of the 1,3,5\_cyclooctatriene (L) -bicyclo[4.2.0]octadiene (3) valence -0 I / -CD \ 1 2 tautomerism as a function of the substituents at C-7 and C-8 (cf. &).2 The German group has concluded
Available literature data about keto-enol equilibrium in b-diketones with different substituents in b-positions (R1C(O)-CH 2 -C(O)R2) has been analyzed. It was concluded that substituents from group I (R = H, CH 3 , CF 3 , C(CH3) 3 ) strongly favour the enol tautomer, whereas substituents from group