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Tandem ruthenium-catalyzed rearrangement/oxidation of bicyclic [2.2.1] heptane epoxides

✍ Scribed by A. Tenaglia; E. Terranova; B. Waegell


Book ID
104244845
Publisher
Elsevier Science
Year
1989
Tongue
French
Weight
118 KB
Volume
30
Category
Article
ISSN
0040-4039

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The title heterocycles rearrange into a mixture of diastereoisomeric hexahydro-l(ZH)-pentalenone derivatives, which undergo nucleophilic eliminative ring fission by methanol to give I-amino-2-nitroalkylated cyclopentancarboxylic esters. The X-ray structure determination of hexahydro-2-methyl-2-nitro