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Tandem Pd/C‐Catalyzed Reductive Coupling and Dehalogenation of Benzylic Halides

✍ Scribed by Joshi, Ashutosh V.; Baidossi, Mubeen; Taha, Nimer; Mukhopadhyay, Sudip; Sasson, Yoel

Book ID
126734750
Publisher
Taylor and Francis Group
Year
2005
Tongue
English
Weight
107 KB
Volume
35
Category
Article
ISSN
0039-7911

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✍ Sigeru Torii; Hideo Tanaka; Kazuo Morisaki 📂 Article 📅 1985 🏛 Elsevier Science 🌐 French ⚖ 207 KB

An efficient electro-reductive coupling of aryl bromides and iodides into biaryls has been performed by the electrolysis with Pd(O)and/or Pd(II)-catalysts in a DMF-Et4NOTs-(Pb cathode) system. I-Bromoand 2-bromopyridines were also converted into the corresponding bipyridyls, respectively. Electra-r