Tandem Claisen-Diels-Alder reactions in synthesis. A facile approach to anthracyclines
β Scribed by Kraus, George A.; Fulton, Brian S.
- Book ID
- 127322406
- Publisher
- American Chemical Society
- Year
- 1985
- Tongue
- English
- Weight
- 377 KB
- Volume
- 50
- Category
- Article
- ISSN
- 0022-3263
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π SIMILAR VOLUMES
Absbactz 4-O.w-2-cyclopentenyl acetate has been shown to behave as a conjunciive reagent for Tandem Diels-Alder Reaction under CJwninum chloriak catalysis. This m&odologyrqwentsamildand -chboparion ofhydrqtkwwnes. Snuciure analysisoftheleaclionproductsbyNMRspectnwcopyi?dircussed Development of metho
The title compound has been prepared by a route involving as the key steps the intramolecular Diels-Alder addition between a furan and a pendant acetylenic ester, and the subsequent retro-Diels-Alder fragmentation of the adduct, induced by 3,6-dicpyridin-2'-yl)-s-tetrazine.