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Tandem Catalytic Carbene Addition/Bicyclization of Enynes. One-Step Synthesis of Fluorinated Bicyclic Amino Esters by Ruthenium Catalysis.

โœ Scribed by Matthieu Eckert; Florian Monnier; Grigorii T. Shchetnikov; Igor D. Titanyuk; Serguej N. Osipov; Loic Toupet; Sylvie Derien; Pierre H. Dixneuf

Publisher
John Wiley and Sons
Year
2006
Weight
28 KB
Volume
37
Category
Article
ISSN
0931-7597

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โœ Dr. Matthieu Eckert; Dr. Solenne Moulin; Dr. Florian Monnier; Dr. Igor D. Titany ๐Ÿ“‚ Article ๐Ÿ“… 2011 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 332 KB

The reaction of fluorinated 1,6- and 1,7-enynes, containing the moiety N(PG)C(CF(3))(CO(2)R), with diazo compounds in the presence of [RuCl(cod)(Cp\*)] (cod=cycloocta-1,5-diene, Cp\*=C(5)Me(5) , PG=protecting group) as the catalyst precursor leads to the formation of fluorinated 3-azabicyclo[3.1.0]h