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Tandem Carbocupration/Oxygenation of Terminal Alkynes

✍ Scribed by Zhang, Donghui; Ready, Joseph M.


Book ID
126082038
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
57 KB
Volume
7
Category
Article
ISSN
1523-7060

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Tandem Silylformylation/Wittig Olefinati
✍ Peter Eilbracht; Christoph Hollmann; AxelΒ M. Schmidt; Lars BΓ€rfacker πŸ“‚ Article πŸ“… 2000 πŸ› John Wiley and Sons 🌐 English βš– 219 KB πŸ‘ 1 views

The rhodium(I)-catalysed sequential silylformylation/Wittig olefination of terminal alkynes with hydrosilanes and carbon monoxide in the presence of stabilised P-ylides leads to substituted 2,4-dienoic esters in a one-pot procedure. The