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Tandem Allylboration—Ring Closing Metathesis Reactions for the Preparation of Biologically Active Molecules

✍ Scribed by P. Veeraraghavan Ramachandran; M. Venkat Ram Reddy; Herbert C. Brown

Publisher
John Wiley and Sons
Year
2004
Weight
53 KB
Volume
35
Category
Article
ISSN
0931-7597

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Ring-Closing Metathesis in the Synthesis
Ring-Closing Metathesis in the Synthesis of Biologically Active Peptidomimetics of Apicidin A
✍ Prashant H. Deshmukh; Carsten Schulz-Fademrecht; Panayiotis A. Procopiou; David  📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 161 KB 👁 2 views

## Abstract Syntheses of novel 16‐membered macrocyclic peptidomimetics are reported, which employ iterative peptide coupling followed by high yielding ring‐closing metathesis (RCM) as the key cyclization step. The target macrocyclic compounds include examples containing a (2__S__)‐amino‐8‐oxodecano