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Tandem 1,4-Addition Reactions with Benzene and Alkylated Benzenes Promoted by Pentaammineosmium(II)

✍ Scribed by Ding, Fei; Kopach, Michael E.; Sabat, Michal; Harman, W. Dean


Book ID
126198082
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
159 KB
Volume
124
Category
Article
ISSN
0002-7863

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## Abstract Alkyl 2‐nitroethanoates react with alkyl propiolates in the presence of triphenylphosphine (Ph~3~P) in a mechanistically unprecedented reaction to afford tetraalkyl benzene‐1,2,3,5‐tetracarboxylates in moderate yields (36–42%).