✦ LIBER ✦
t-Butyl alcohol-assisted fission of the P-P bonds in red phosphorus with lithium in liquid ammonia: A convenient preparative method for dialkylphosphanes
✍ Scribed by S.N. Arbuzova; N.K. Gusarova; B.A. Trofimov; L. Brandsma
- Book ID
- 104589686
- Publisher
- Elsevier Science
- Year
- 2010
- Tongue
- English
- Weight
- 118 KB
- Volume
- 113
- Category
- Article
- ISSN
- 0165-0513
No coin nor oath required. For personal study only.
✦ Synopsis
Abstract
Essentially complete fission of the P‐P bonds in red phosphorus can be effected by adding one equivalent of t‐butylalcohol to a mixture of red P and lithium in liquid ammonia. The reaction has been applied to synthesize some dialkylphosphanes.