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Systematic trends in the synthesis of (meta-phenylene vinylene) copolymers

✍ Scribed by A. Drury; S. Maier; A.P. Davey; A.B. Dalton; J.N. Coleman; H.J. Byrne; W.J. Blau


Book ID
117538216
Publisher
Elsevier Science
Year
2001
Tongue
English
Weight
256 KB
Volume
119
Category
Article
ISSN
0379-6779

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The Gilch Synthesis of Poly(p-phenylene
✍ Thorsten Schwalm; Jens Wiesecke; Stefan Immel; Matthias Rehahn πŸ“‚ Article πŸ“… 2009 πŸ› John Wiley and Sons 🌐 English βš– 779 KB

## Abstract A consistent picture is presented of the mechanistic details and intermediates of the Gilch polymerization leading to poly(__p__‐phenylene vinylenes) (PPVs). In‐situ generated __p__‐quinodimethanes are shown to be the real monomers, and spontaneous formation of the initiating radicals i