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Systematic Analysis of the Intramolecular Competition Associated with the Ring Closing Metathesis of Ene-Diene Systems of Differing Chain Length with a Pair of Ruthenium Catalysts

✍ Scribed by Leo A. Paquette; Kallol Basu; James C. Eppich; John E. Hofferberth

Publisher: John Wiley and Sons
Year: 2002
Tongue: German
Weight: 259 KB
Volume: 85
Category: Article
ISSN: 0018-019X
DOI: 10.1002/1522-2675(200210)85:10<3033::aid-hlca3033>3.0.co;2-2

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✍ Kallol Basu; James C. Eppich; Leo A. Paquette 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 66 KB

The course of ring-closing metathesis of a series of ene-dienes has been examined for its regioand stereoselectivity. Each example studied gave rise predominantly or exclusively to a cyclization product of a specific structural type. Each of the four possible mechanistic pathways are represented. Th