𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Synthèse de spirohydantoines dérivées du diphényl-2,4-aza-3-bicyclo-[3.3.1]nonane et du diphényl-7,9-aza-8-bicyclo[4.3.1]decane par réaction de Bucherer dans la N,N-diméthylformamide: Influence de la température et cours stéréochimique. Communication préliminaire

✍ Scribed by Ernesto Martínez; Carmen del Campo; Gregorio G. Trigo

Publisher
John Wiley and Sons
Year
1983
Tongue
German
Weight
212 KB
Volume
66
Category
Article
ISSN
0018-019X

No coin nor oath required. For personal study only.

✦ Synopsis

Synthesis of Spyrohydantoines Derivatives of 2,4‐Diphenyl‐3‐azabicyclo[3.3.1]nonane and 7,9‐Diphenyl‐8‐azabicyclo[4.3.1]decane via Bucherer Reaction in N,N‐Dimethylformamide: Influence of the Temperature and Stereochemical Path

The unreactives ketones related to 2,4‐diphenyl‐3‐azabicyclo [3.3.1]nonan‐9‐one to the Bucherer reaction in usuals conditions show excellent reactivity in DMF. as unique solvant. The stereochemical paths of these reactions and the synthetic utility of the temperature modification are described.

📜 SIMILAR VOLUMES

Synthèse facile de dérivés du diphényl-2
Synthèse facile de dérivés du diphényl-2,4-aza-3-bicyclo[3.3.1]nonane et du diphényl-7,8-aza-8-bicyclo[4.3.1]décane
✍ Carmen Del Campo; Ernesto Martinez; Gregorio G. Trigo 📂 Article 📅 1984 🏛 John Wiley and Sons 🌐 German ⚖ 335 KB 👁 1 views

**Facile synthesis of derivatives of 2,4‐diphenyl‐3‐azabicyclo[3.3.1]nonane and 7,9‐diphenyl‐8‐azabicyclo[4.3.1]decane** The facile synthesis of hydantoins, cyanhydrins and aminonitriles derived from 2,4‐diphenyl‐3‐azabicyclo[3.3.1]nonanone and 7,9‐diphenyl‐8‐azabicyclo[4.3.1]decanone is described.