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Synthetic studies towards furanocembrane diterpenes. A total synthesis of bis-deoxylophotoxin

✍ Scribed by Cases, Manuel; Gonzalez-Lopez de Turiso, Felix; Hadjisoteriou, Maria S.; Pattenden, Gerald


Book ID
120532733
Publisher
Royal Society of Chemistry
Year
2005
Tongue
English
Weight
478 KB
Volume
3
Category
Article
ISSN
1477-0520

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Indole-Diterpene Synthetic Studies: Tota
✍ Amosβ€…B. Smith III; Haifeng Cui πŸ“‚ Article πŸ“… 2003 πŸ› John Wiley and Sons 🌐 German βš– 522 KB

## Abstract An efficient, stereocontrolled total synthesis of the complex indole‐diterpene alkaloid (βˆ’)‐21‐isopentenylpaxilline (**1**) has been achieved. Key elements of the synthesis include the stereocontrolled construction of the advanced eastern hemisphere (βˆ’)‐**68**, involving a highly effici