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Synthetic studies relevant to biosynthetic research on vitamin B. Part 3. An approach to isobacteriochlorins via nitrones

✍ Scribed by Battersby, Alan R.; Reiter, Lawrence A.


Book ID
121732034
Publisher
Royal Society of Chemistry
Year
1984
Weight
863 KB
Category
Article
ISSN
1472-7781

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Synthetic Studies on Coenzyme Q10. Part
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An efficient and stereoselective approach to the synthesis of coenzyme Q 10 is described (Scheme). The MeOCH 2 -protected p-hydroquinone 4 containing the C 5 (E)-allyl (tert-butyl)dimethylsilyl ether moiety was obtained via a halogen -lithium exchange of the MeOCH 2 -proctected 2-bromo-5,6dimethoxy-