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Synthetic studies on tetrahydropyrroloquinoline-containing natural products: Syntheses of discorhabdin C, batzelline C and isobatzelline C

✍ Scribed by Xue Liang Tao; Ji-Fei Cheng; Shigeru Nishiyama; Shosuke Yamamura

Book ID: 104203102
Publisher: Elsevier Science
Year: 1994
Tongue: French
Weight: 1019 KB
Volume: 50
Category: Article
ISSN: 0040-4020
DOI: 10.1016/s0040-4020(01)85065-1

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✦ Synopsis

Discorhabdin C (1). batze.lline C (2) and isobafze-lline C (3). metabolites of marine sources sharing a tetrahydropyrroloquinoline core, have been successfully synthesized, and cytotexicities of several sydlhetic intmnedkswereevahtaM. Among physiologically active substances isolated from marine sources, the pyrroloquinoline alkaloid family consisting of prianosinst [Prianos melanos: discorhabdins* (L.utrunculia du Bocage, Lotrunctdia brevis and Prianas sp.)], batzellins (Batzella sp.),3 wakayin (Clavelina sp.)P damirones (Damiria sp.)s and makaluvamines (Zyzzya cf. marsailis and Histodennella 8p.F exhibits antitumor activities derived from the unique highly-fused structmes. Particularly, the novel sulfur-containing alkaloid structure of prianosin A (discorhabdin A) has served

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