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Synthetic Studies on Maitotoxin. 3. Stereoselective Synthesis of the BCDE-Ring System

โœ Scribed by Satoh, Masanori; Koshino, Hiroyuki; Nakata, Tadashi


Book ID
127127469
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
329 KB
Volume
10
Category
Article
ISSN
1523-7060

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Synthetic studies on brevetoxin-B. Part
โœ Hiroko Matsukura; Nobuyuki Hori; Goh Matsuo; Tadashi Nakata ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 96 KB

The IJK-ring system of brevetoxin-B was stereoselectively synthesized based on the 6-endo-cyclizations of a hydroxy methylepoxide and a hydroxy styrylepoxide, and the direct introduction of the C-4 unit as the side chain.