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Synthetic studies on clerodane diterpenoids. 4. The total synthesis of (±)-6β-acetoxy-2-oxokolavenool

✍ Scribed by Hsing-Jang Liu; Kak-Shan Shia


Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
599 KB
Volume
54
Category
Article
ISSN
0040-4020

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✦ Synopsis


The first total synthesis of the title compound in racemic form has been accomplished from ketone 4, a readily accessible compound via an intermolecular Diels-Alder approach developed previously for the synthesis of clerodane diterpenoids.


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✍ H.-J. LIU; K.-S. SHIA 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 38 KB 👁 2 views

Synthetic Studies on Clerodane Diterpenoids. Part 4. The Total Synthesis of (±)-6β-Acetoxy-2-oxokolavenool. -The title compound (X) belongs to the class of clerodane diterpenoids which possess interesting antifeedant and medicinal properties and are potentially useful as insecticidal, antitumor, an