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Synthetic Studies of Furanosesquiterpenoid Tetrahydrolinderazulenes. Total Synthesis of (.+-.)-Echinofuran.

✍ Scribed by Ho-Kee Yim; Yun Liao; Henry N. C. Wong


Book ID
101940512
Publisher
John Wiley and Sons
Year
2003
Weight
182 KB
Volume
34
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

For Abstract see ChemInform Abstract in Full Text.


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## Abstract An efficient, stereocontrolled total synthesis of the complex indole‐diterpene alkaloid (βˆ’)‐21‐isopentenylpaxilline (**1**) has been achieved. Key elements of the synthesis include the stereocontrolled construction of the advanced eastern hemisphere (βˆ’)‐**68**, involving a highly effici