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Synthetic Routes to N-Heterocyclic Carbene Complexes: Pyridine–Carbene Tautomerizations

✍ Scribed by Doris Kunz

Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
636 KB
Volume
46
Category
Article
ISSN
0044-8249

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A General Synthetic Route to Mixed NHC–P
A General Synthetic Route to Mixed NHC–Phosphane Palladium(0) Complexes (NHC=N-Heterocyclic Carbene)
✍ Serena Fantasia; Steven P. Nolan 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 341 KB 👁 2 views

## Abstract Mixed NHC–phosphane palladium(0) complexes [(NHC)Pd(PR~3~)] (NHC: N‐heterocyclic carbene) are synthesized directly from commercially available reagents, with the possibility to tune the nature of both the NHC and the phosphane. Reaction of [(NHC)Pd(allyl)Cl] (palladium source) and PR~3~