Synthetic routes to cyclopropylidenecarbinols and to cyclopropylidienes
โ Scribed by S. Halazy; A. Krief
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- French
- Weight
- 197 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0040-4039
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Synthetic patha to crfrbtic add derfvutfvea are expJored and a convergent mute to the total syntbesim of tbsm moleculea in dsmcribed. Criatatic acid (l), a farneayl phenol modified by incorporation of a furan ring in ita dde chain, waa inolated fmm the fruiting bodies of AJbatreJJu~ crJAatue by Step
## Abstract Two routes to 1,4โdifunctionalized cycloheptenes are described. The first one is based on a fluorideโinduced fragmentation reaction of the bicyclic [3.2.0]heptanesilyl monosulfate 10. This compound in turn was prepared by a keteneโcyclopentene cycloaddition route. An alternative strateg