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Synthetic models for catechol 1,2-dioxygenases. Interception of a metal catecholate-dioxygen adduct

✍ Scribed by Barbaro, Pierluigi; Bianchini, Claudio; Mealli, Carlo; Meli, Andrea


Book ID
120194202
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
424 KB
Volume
113
Category
Article
ISSN
0002-7863

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## Abstract A series of mononuclear iron(III) complexes as models for intradiol cleaving catechol dioxygenases has been synthesized. In all six compounds, the iron(III) core is coordinated by the ligand [(6‐bromo‐2‐pyridyl)methyl]bis[(2‐pyridyl)methyl]amine (brtpa) which mimics the endogenous ligan