Structural Snapshots of a Dynamic Coordi
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Michael Merkel; David Schnieders; SaschaΒ M. Baldeau; Bernt Krebs
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Article
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2004
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John Wiley and Sons
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English
β 219 KB
## Abstract A series of mononuclear iron(III) complexes as models for intradiol cleaving catechol dioxygenases has been synthesized. In all six compounds, the iron(III) core is coordinated by the ligand [(6βbromoβ2βpyridyl)methyl]bis[(2βpyridyl)methyl]amine (brtpa) which mimics the endogenous ligan