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SYNTHETIC INVESTIGATIONS IN THE CAMPHOR SERIES. PART IV. STUDY OF INTRAMOLECULAR CYCLIZATION OF TRIETHYL 2-METHYLHEXANE-2,3,6-TRICARBOXYLATE

โœ Scribed by TALUKDAR, P. B.; BAGCHI, P.


Book ID
126873980
Publisher
American Chemical Society
Year
1955
Tongue
English
Weight
522 KB
Volume
20
Category
Article
ISSN
0022-3263

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Diastereoselective construction of cis 2
โœ Teck-Peng Loh; Jian-Ying Yang; Li-Chun Feng; Yan Zhou ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 129 KB

Diastereoselective construction of 2,6-disubstituted tetrahydropyrans with an exocyclic double bond was achieved via the In(OTf) 3 -catalyzed intramolecular 2,5-oxonium-ene cyclization. Its application was further demonstrated by the synthesis of a common intermediate for both zampanolide and dactyl